<html><head><meta http-equiv="content-type" content="text/html; charset=utf-8"></head><body dir="auto"><div>Dear Greg</div><div><br></div><div>Thanks for the detailed analysis...</div><div><br></div><div>I note that hydrogen, CO, CH4 Argon +O2 and N2 make up about 99% of the total.   Interesting that there are so many other minor constituents requiring mass spec analysis, and probably missed by early analyses.  Do you have a calculated energy content (kJ/m^3 or Btu/ft^3) for this particular analysis?</div><div><br></div><div>Thanks a bunch..</div><div><br></div><div>Tom Reed</div><div><br></div><div>(aka)<br><br>Dr. Thomas B Reed<span class="Apple-style-span" style="-webkit-tap-highlight-color: rgba(26, 26, 26, 0.296875); -webkit-composition-fill-color: rgba(175, 192, 227, 0.230469); -webkit-composition-frame-color: rgba(77, 128, 180, 0.230469); "> </span><div><span class="Apple-style-span" style="-webkit-tap-highlight-color: rgba(26, 26, 26, 0.292969); -webkit-composition-fill-color: rgba(175, 192, 227, 0.230469); -webkit-composition-frame-color: rgba(77, 128, 180, 0.230469);">280 Hardwick Rd</span></div><div><span class="Apple-style-span" style="-webkit-tap-highlight-color: rgba(26, 26, 26, 0.292969); -webkit-composition-fill-color: rgba(175, 192, 227, 0.230469); -webkit-composition-frame-color: rgba(77, 128, 180, 0.230469);">Barre, MA 01005</span></div><div><span class="Apple-style-span" style="-webkit-tap-highlight-color: rgba(26, 26, 26, 0.292969); -webkit-composition-fill-color: rgba(175, 192, 227, 0.230469); -webkit-composition-frame-color: rgba(77, 128, 180, 0.230469);"><br></span></div><div><span class="Apple-style-span" style="-webkit-tap-highlight-color: rgba(26, 26, 26, 0.292969); -webkit-composition-fill-color: rgba(175, 192, 227, 0.230469); -webkit-composition-frame-color: rgba(77, 128, 180, 0.230469);">508 353 7841</span></div></div><div><br>On Mar 25, 2013, at 1:57 PM, Greg Manning <<a href="mailto:a31ford@gmail.com">a31ford@gmail.com</a>> wrote:Being speculative based on some known facts, I would assume that since 1 ton of biomass (based on Ideal Gasifiction (NOT "syngas", but rather "woodgas" or "producer gas", an average of small gasifiers is a common CO2 output of approximately 11 to 30 % by volume (See sample GCMS report below)</div><blockquote type="cite"><div>
<br></div><div>It would be a qualified guess to say, 7 to 8 tons of biomass, BASED on reasonable gasification of the said biomass. I am NOT considering incineration, ONLY "home made" gasification.</div><div><br>
</div><div>Greg Manning,</div><div><a href="http://www.cangas.ca">www.cangas.ca</a><br><div><br></div><div><div>==========================================                   </div><div>                                                                                </div>
<div>                   |  RT   |   Compound Name    |  Amount   |                   </div><div>                   | (min) |                    |    %      |                   </div><div>                   -------------------------------------------                  </div>
<div>                   |  1.164|hydrogen            |     11.22 |                   </div><div>                   |  2.251|C7+                 |      0.03 |                   </div><div>                   |  2.399|carbon dioxide      |     12.79 |                   </div>
<div>                   |  3.209|methane             |      1.06 |                   </div><div>                   |  3.347|ethane              |      0.06 |                   </div><div>                   |  3.473|ethylene            |      0.18 |                   </div>
<div>                   |  3.857|propane             |      0.01 |                   </div><div>                   |  0.000|cyclopropane        |      0.00 |                   </div><div>                   |  4.537|propylene           |      0.04 |                   </div>
<div>                   |  4.935|acetylene           |      0.00 |                   </div><div>                   |  5.138|isobutane           |      0.00 |                   </div><div>                   |  5.191|propadiene          |      0.00 |                   </div>
<div>                   |  5.326|n-butane            |      0.00 |                   </div><div>                   |  0.000|hydrogen sulfide    |      0.00 |                   </div><div>                   |  6.280|t-2 butene          |      0.00 |                   </div>
<div>                   |  6.362|1-butene            |      0.00 |                   </div><div>                   |  6.536|isobutylene         |      0.00 |                   </div><div>                   |  6.701|c-2-butene          |      0.00 |                   </div>
<div>                   |  0.000|isopentane          |      0.00 |                   </div><div>                   |  7.407|n-pentane           |      0.00 |                   </div><div>                   |  7.579|1,3 butadiene       |      0.01 |                   </div>
<div>                   |  7.807|argon-oxygen        |      6.84 |                   </div><div>                   |  7.961|3-methyl-1-butene   |      0.00 |                   </div><div>                   |  8.090|t-2-pentene         |      0.00 |                   </div>
<div>                   |  8.155|nitrogen            |     61.36 |                   </div><div>                   |  8.240|2-methyl-2-butene   |      0.00 |                   </div><div>                   |  8.296|1-pentene           |      0.00 |                   </div>
<div>                   |  8.338|2-methyl-1-butene   |      0.00 |                   </div><div>                   |  8.453|c-2-pentene         |      0.00 |                   </div><div>                   |  9.250|C6+                 |      0.02 |                   </div>
<div>                   |  9.886|carbon monoxide     |      6.37 |                   </div><div>                                                                                </div><div>                     Total                           100.00                     </div>
<div>                                                                                </div><div>                   ==========================================  </div><br><div class="gmail_quote">On Fri, Aug 19, 2011 at 12:35 PM, A.Saravanakumar <span dir="ltr"><<a href="mailto:sara_mnes@rediffmail.com" target="_blank">sara_mnes@rediffmail.com</a>></span> wrote:<br>
<blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex">Dear Booster Reed,<br>
<br>
How much ton of biomass will burn to produce 1 ton of CO2?<br>
<br>
A. Saravanakumar<br>
<br>
On Fri, 19 Aug 2011 00:38:55 +0530  wrote<br>
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Today's Topics:<br>
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<br>
<br>
  1. Re: CO2 emission of whole system for smaall size generator<br>
<br>
   (20kWe) (GF)<br>
<br>
  2. Re: CO2 emission of whole system for smaall size generator<br>
<br>
   (20kWe) (Arnt Karlsen)<br>
<br>
  3. Re: CO2 emission of whole system for smaall sizegenerator<br>
<br>
   (20kWe) (Thomas Reed)<br>
<br>
<br>
<br>
<br>
<br>
----------------------------------------------------------------------<br>
<br>
<br>
<br>
Message: 1<br>
<br>
Date: Wed, 17 Aug 2011 21:04:26 -0400 (EDT)<br>
<br>
From: GF <u></u><br>
<br>
To: <a href="mailto:gasification@lists.bioenergylists.org" target="_blank">gasification@lists.bioenergylists.org</a><br>
<br>
Subject: Re: [Gasification] CO2 emission of whole system for smaall<br>
<br>
size generator (20kWe)<br>
<br>
Message-ID: <<a href="mailto:8CE2B59E894A95D-1C20-23C51@Webmail-m104.sysops.aol.com" target="_blank">8CE2B59E894A95D-1C20-23C51@Webmail-m104.sysops.aol.com</a>><br>
<br>
Content-Type: text/plain; charset="utf-8"<br>
<br>
<br>
<br>
<br>
<br>
It is a little known fact that CO2 can be converted into Methane. Years <br>
ago this was expensive and quite a difficult reaction to perform, <br>
involving very high pressure and temperature reaction chambers together <br>
with exotic catalysts. However,over the years since "Sabatier" <br>
discovered how to perform this remarkable feat, fuel and chemical <br>
refiners have developed a lower cost approach. But fairly high <br>
temperatures are still required, making the process expensive. <br>
Fortunately, there is considerable waste heat available at the exhaust <br>
manifold of your Engine to supplant some of this cost. Additional heat <br>
is also required in order to re-arrange the molecules back into fuel, <br>
this is where a stream of hydrogen from an out side source such as your <br>
gasifier will help, as will super heated distilled water. The <br>
additional heat can be provided by a plasma produced by an arc or an <br>
electrode less plasma produced by Electromagnetic means. nothing more <br>
than 2kw. <br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
GF  <br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
-----Original Message-----<br>
<br>
From: J?r?mie Biton <u></u><br>
<br>
To: gasification <u></u><br>
<br>
Sent: Wed, Aug 17, 2011 9:45 am<br>
<br>
Subject: [Gasification] CO2 emission of whole system for smaall size <br>
generator (20kWe)<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
Hello to all,<br>
<br>
 <br>
<br>
Does anybody have an idea of the CO2 emission after generator?<br>
<br>
For comparison, a diesel generator of this size (20kWe) has a rate of <br>
about 1,1 kgeqCO2/kWh.<br>
<br>
 <br>
<br>
Thanks <br>
<br>
Regards<br>
<br>
 <br>
<br>
Jeremy<br>
<br>
<br>
<br>
<br>
<br>
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Message: 2<br>
<br>
Date: Thu, 18 Aug 2011 08:46:39 +0200<br>
<br>
From: Arnt Karlsen <u></u><br>
<br>
To: <a href="mailto:gasification@lists.bioenergylists.org" target="_blank">gasification@lists.bioenergylists.org</a><br>
<br>
Subject: Re: [Gasification] CO2 emission of whole system for smaall<br>
<br>
size generator (20kWe)<br>
<br>
Message-ID: <20110818084639.0748c1ee@celsius.lan><br>
<br>
Content-Type: text/plain; charset=US-ASCII<br>
<br>
<br>
<br>
On Wed, 17 Aug 2011 21:04:26 -0400 (EDT), GF wrote in message <br>
<br>
<<a href="mailto:8CE2B59E894A95D-1C20-23C51@Webmail-m104.sysops.aol.com" target="_blank">8CE2B59E894A95D-1C20-23C51@Webmail-m104.sysops.aol.com</a>>:<br>
<br>
<br>
<br>
> <br>
<br>
> It is a little known fact that CO2 can be converted into Methane.<br>
<br>
> Years ago this was expensive <br>
<br>
<br>
<br>
..still is: <br>
<br>
<a href="http://en.wikipedia.org/wiki/Methane#Atmospheric_methane" target="_blank">http://en.wikipedia.org/wiki/Methane#Atmospheric_methane</a><br>
<br>
<br>
<br>
-- <br>
<br>
..med vennlig hilsen = with Kind Regards from Arnt Karlsen<br>
<br>
...with a number of polar bear hunters in his ancestry...<br>
<br>
 Scenarios always come in sets of three: <br>
<br>
 best case, worst case, and just in case.<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
------------------------------<br>
<br>
<br>
<br>
Message: 3<br>
<br>
Date: Wed, 17 Aug 2011 21:38:05 -0400<br>
<br>
From: Thomas Reed <u></u><br>
<br>
To: Discussion of biomass pyrolysis and gasification<br>
<br>
<u></u><br>
<br>
Cc: "<u></u>"<br>
<br>
<u></u><br>
<br>
Subject: Re: [Gasification] CO2 emission of whole system for smaall<br>
<br>
sizegenerator (20kWe)<br>
<br>
Message-ID: <u></u><br>
<br>
Content-Type: text/plain; charset="utf-8"<br>
<br>
<br>
<br>
Jeremy and all<br>
<br>
<br>
<br>
Both gasoline and diesel are approximately -CH2- chained together. <br>
Their combustion can be written<br>
<br>
 <br>
<br>
CH2 + 3/2(O2 + 3.76 N2) ==> CO2 + H2O + 5.64 N2<br>
<br>
M 14.                    44.   18      158.       220<br>
<br>
<br>
<br>
So the all important Air/Fuel, A/F ratio is 220 /14= 15.7<br>
<br>
<br>
<br>
The ratio is often given as 14.7. Maybe this is due to the presence of <br>
unsaturated and aromatics with lower H/C ratios.<br>
<br>
<br>
<br>
The oxygen sensor is capable of measuring very small amounts of <br>
unburned fuel or oxygen in the exhaust and adjusting the A/F ratio for <br>
perfect combustion. <br>
<br>
<br>
<br>
Diesel combustion is always lean.<br>
<br>
<br>
<br>
Lucky us that our cars are so clean.<br>
<br>
<br>
<br>
Tom Reed<br>
<br>
<br>
<br>
<br>
<br>
<br>
<br>
On Aug 17, 2011, at 9:44 AM, J?r?mie Biton <u></u> wrote:<br>
<br>
<br>
<br>
> Hello to all,<br>
<br>
> <br>
<br>
> <br>
<br>
> <br>
<br>
> Does anybody have an idea of the CO2 emission after generator?<br>
<br>
> <br>
<br>
> For comparison, a diesel generator of this size (20kWe) has a rate of <br>
about 1,1 kgeqCO2/kWh.<br>
<br>
> <br>
<br>
> <br>
<br>
> <br>
<br>
> Thanks<br>
<br>
> <br>
<br>
> Regards<br>
<br>
> <br>
<br>
> <br>
<br>
> <br>
<br>
> Jeremy<br>
<br>
> <br>
<br>
> _______________________________________________<br>
<br>
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End of Gasification Digest, Vol 12, Issue 13<br>
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</blockquote><blockquote type="cite"><div><span>_______________________________________________</span><br><span>Gasification mailing list</span><br><span></span><br><span>to Send a Message to the list, use the email address</span><br><span><a href="mailto:Gasification@bioenergylists.org">Gasification@bioenergylists.org</a></span><br><span></span><br><span>to UNSUBSCRIBE or Change your List Settings use the web page</span><br><span><a href="http://lists.bioenergylists.org/mailman/listinfo/gasification_lists.bioenergylists.org">http://lists.bioenergylists.org/mailman/listinfo/gasification_lists.bioenergylists.org</a></span><br><span></span><br><span>for more Gasifiers,  News and Information see our web site:</span><br><span><a href="http://gasifiers.bioenergylists.org/">http://gasifiers.bioenergylists.org/</a></span><br></div></blockquote></body></html>