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</o:shapelayout></xml><![endif]--></head><body bgcolor=white lang=EN-US link="#1E66AE" vlink="#1E66AE"><div class=WordSection1><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Crispin, <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Lots of work was done on bark utilization by Jean Mater, Mater Engineering, from about 1945 on. Her work is in USFS publications. Jean died a couple of years ago. When the US National Renewable Energy Laboratory (NREL)was researching fast pyrolysis the principal contractor (Midwest Research) patented several chemicals from bark pyrolysis with major wood industries. They were mostly resins for use as industrial adhesives. I think Ensyn (Canada) also has a process to make adhesives from pyrolysis products. As far as I know these products are not in commercial use. <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>I'm sure that the cost to make charcoal for Maputo is considerably lower than here. One challenge for Southern Africa is how to make the portable metal bush kilns more efficient and environmentally friendly while keeping the cost and capital low enough to benefit the population that is now making charcoal. How can you make kilns that are more attractive than earth kilns? It's hard to beat labor vs capital. <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Oil making pyrolyzers have substantial capital investments. 70% yield oil (15% char + 15% gas) requires an industrial plant (Dynamotive, Ensysn). Either the gas or char is consumed in the process. Slow pyrolysis yields about equal quantities of oil, char and gas. In both cases you are externally heating the wood at about 450C. For high oil yields the wood is finely divided and typically pyrolyzed using an externally heated sand carrier, as in a circulating fluidized bed. <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Manuel Garcia Perez, Washington State University, provided a nice overview of pyrolysis technologies in his November presentation at a Washington Future Energy Conference:<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>http://www.futureenergyconference.com/2010/FECWA-Presentations/4D_Garcia.pdf<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Gasifiers yield 2-5% char and gas and tars. Reaction temperatures are about 800C for the char. The beauty of the TLUD is the gas yield for cooking and a higher yield of char. <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Tom<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><div><div style='border:none;border-top:solid #B5C4DF 1.0pt;padding:3.0pt 0in 0in 0in'><p class=MsoNormal><b><span style='font-size:10.0pt;font-family:"Tahoma","sans-serif"'>From:</span></b><span style='font-size:10.0pt;font-family:"Tahoma","sans-serif"'> stoves-bounces@lists.bioenergylists.org [mailto:stoves-bounces@lists.bioenergylists.org] <b>On Behalf Of </b>Crispin Pemberton-Pigott<br><b>Sent:</b> Monday, December 20, 2010 3:30 AM<br><b>To:</b> 'Discussion of biomass cooking stoves'<br><b>Subject:</b> Re: [Stoves] [biochar] Capturing carbon in the timber industry<o:p></o:p></span></p></div></div><p class=MsoNormal><o:p> </o:p></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Dear Tom<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Is there perhaps valuable oil in the bark not found in the wood?<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>The $150 is just below the street price of charcoal in Maputo so it is high. One certainly could not <i>bury</i> that much money.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Do you happen to know the charring temperature for (predominantly) oil in the output?<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Thanks<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Crispin<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p></div></body></html>