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</o:shapelayout></xml><![endif]--></head><body lang=EN-US link=blue vlink=purple><div class=WordSection1><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Stovers,<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>It seems testing for pm seems pointless in some ways in that don’t they form based on cooling temperatures change in air flow and moisture content etc.? So depending on ‘snap shot’ in time and location they will differ in size and problem. Since pm is from organics larger than CO or CO2 having potential to form particles we should focus on a measure of complex organics left over leaving the stack. Thinking pulling gas into a tube that re-heats and oxidizes, comparing CO2 before and increase after, to determine pm potential. Why spend so much time and interest in pm measuring when its formation is so elusive? <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Frank<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Frank Shields<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Control Laboratories, Inc.<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>42 Hangar Way<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Watsonville, CA 95076<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>(831) 724-5422 tel<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>(831) 724-3188 fax<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><a href="http://www.biocharlab/"><span style='color:blue'>www.biomasslab</span></a>.com<o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'> <o:p></o:p></span></p><p class=MsoNormal><span style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><div><div style='border:none;border-top:solid #B5C4DF 1.0pt;padding:3.0pt 0in 0in 0in'><p class=MsoNormal><b><span style='font-size:10.0pt;font-family:"Tahoma","sans-serif"'>From:</span></b><span style='font-size:10.0pt;font-family:"Tahoma","sans-serif"'> stoves-bounces@lists.bioenergylists.org [mailto:stoves-bounces@lists.bioenergylists.org] <b>On Behalf Of </b>Crispin Pemberton-Pigott<br><b>Sent:</b> Tuesday, June 05, 2012 8:58 AM<br><b>To:</b> 'Discussion of biomass cooking stoves'<br><b>Subject:</b> Re: [Stoves] Improving Thermal Efficiency (TARP-VE)<o:p></o:p></span></p></div></div><p class=MsoNormal><o:p> </o:p></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Dear Dean<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>There are two levels of collection depending on who wants what. We are using a Dusttrak DRX which can measure up to 150 milligrammes per cubic metre. It measures and reports PM 1.0, 2.5, 4.0 and 10 simultaneously. It is a light scattering instrument that can measure down to PM0.1. We also have in JHB a GRIMM 180 aerosol monitor which covers 0.125 to 32 microns in 32 channels.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>In order to collect data from much higher concentrations, the exhaust stream from the stove is captured (or sampled directly from the chimney) and diluted using dry air to get the humidity below the condensation point so as to avoid measuring condensed water droplets as particles. This dilution also considers what the PM level is at the time. It is not a fixed dilution – it can be adjusted at will by an operator. As a result it can cover a range of 2 million to 1 in concentration. LBNL just built a copy of it and said it work right off the bat. <o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Gravimetric confirmation can be provided when someone really wants the info. Deep quartz filters are preferred because they are far easier to work with and the concentrations tend to be high, and the scale needed is not in the same class as that required for IAQ work. Both Profs Annegarn and Lodoysamba have many years experience with outdoor air measurements so we can set up for anything people want to know. <o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>We have always been concentrating on stove development and avoiding certification (many difficult issues) so the setup is aimed at real time measurements so as to find sweet spots and develop them. I don’t have a lot of confidence in light scattering especially or small sizes where the detection efficiency is low. There are good machines around which can detect over 1 billion particles per cubic centimeter and characterise the size and shape simultaneously but budget becomes an issue. A stove development lab just doesn’t need that kind of detail.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>The big issues for anything using a hood (which we use for small stoves) is the condensation of moisture at low dilution rates because it is reported as PM. Really clean stoves produce so little that the temptation to reduce the dilution leads to problems. That assumes of course that the sample is properly dried / condensed. Condensed particles are probably dominant in terms of health effects. To get the particles to condense and keep the moisture in vapour form is the core challenge.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>We have managed to cope with PM up to 17 grammes per cubic metre (O2 factored to 0%). The was measured during the operation of an ‘improved stove’ that was promoted having never been tested.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>As you probably know, we are using a carbon mass balance method of determining the volume of emissions (scale and diluted sample) so there is normally no hood involved. Even when there is, we do not capture the whole volume of emissions, only a sample + the mass burned. This is quite different from the EPA and PEMS hood method. I can’t really comment on the overall accuracy comparison, but the no-hood method copes better I think with moisture in the stack and can handle massive doses of PM early followed by very low levels later.<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Regards<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'>Crispin<o:p></o:p></span></p><p class=MsoNormal><span lang=EN-CA style='font-size:11.0pt;font-family:"Calibri","sans-serif";color:#1F497D'><o:p> </o:p></span></p><p class=MsoNormal style='mso-margin-top-alt:auto;mso-margin-bottom-alt:auto'><span lang=EN-CA>Dear Crispin,<o:p></o:p></span></p><div><p class=MsoNormal style='mso-margin-top-alt:auto;mso-margin-bottom-alt:auto'><span lang=EN-CA>How are you measuring PM in your experiments these days: light scattering, pump and filter, or something else?<o:p></o:p></span></p></div><div><p class=MsoNormal style='mso-margin-top-alt:auto;mso-margin-bottom-alt:auto'><span lang=EN-CA>Best,<o:p></o:p></span></p></div><div><p class=MsoNormal style='mso-margin-top-alt:auto;margin-bottom:12.0pt'><span lang=EN-CA>Dean<o:p></o:p></span></p></div></div></body></html>