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do a google search on : pyrolysis mass flow analysis and see if
that helps you. i think it may well do so if you will spend some
time reading.<br>
<br>
regards,<br>
ronald von den husten<br>
<br>
<div class="moz-cite-prefix">On 23.04.2013 14:21, <a class="moz-txt-link-abbreviated" href="mailto:scda2@t-online.de">scda2@t-online.de</a>
wrote:<br>
</div>
<blockquote cite="mid:1UUcE9-0VJeKm0@fwd01.aul.t-online.de"
type="cite"><font style="font-family: arial,helvetica,sans-serif;"
size="2"><br>
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<p style="line-height: normal;" class="MsoNormal"><span
style="font-size:
10pt;" lang="EN-US">Literature:<br>
</span></p>
<p style="line-height: normal;" class="MsoNormal"><span
style="font-size: 10pt;" lang="EN-US">When the wood is dry
and heated to around
280°C, it begins to
spontaneously break down to produce charcoal plus water
vapor, methanol,
acetic
acid and more complex chemicals, chiefly in the form of tars
and
non-condensable gas consisting mainly of hydrogen, carbon
monoxide and
carbon
dioxide. Air is admitted to the carbonizing kiln or pit to
allow some
wood to
be burned and the nitrogen from this air will also be
present in the
gas. The
oxygen of the air is used up in burning part of the wood
charged.<span> </span>The spontaneous breakdown or
carbonization of
the wood above a temperature of 280°C liberates energy and
hence this
reaction
is said to be <b>exothermic</b>. This process of
spontaneous breakdown
or
carbonization continues until only the carbonized residue
called
charcoal
remains. Unless further external heat is provided, the
process stops and
the
temperature reaches a maximum of about 400°C. <br>
</span></p>
<p style="line-height: normal;" class="MsoNormal"><br>
<span style="font-size: 10pt;" lang="EN-US"></span></p>
<p style="line-height: normal;" class="MsoNormal"><span
style="font-size: 10pt;" lang="EN-US">ADAM:<br>
</span></p>
<p style="line-height: normal;" class="MsoNormal"><span
style="font-size: 10pt; color:
red;" lang="EN-US">Comment: “exothermic” is still <b>a kind
of mystery
for me, </b>because I often realized that If the wood
chamber of a
retort already heats up
to ~300°C – still a lot of heat Is needed from <b>outside</b>
to push
gasification. </span></p>
<p style="line-height: normal;" class="MsoNormal"><span
style="font-size: 10pt; color:
red;" lang="EN-US">I am really tempted to make a laboratory
experiment.
Place a piece of oven dry wood in a small container, and
place it in in
electric oven by 500°C., record the temperature inside the
small
container
wood, ideally the temperature should jump up more quickly
above 280°C,
because
of additional “exothermic” heat supplied from “inside the
wood-charcoal
piece?<br>
<b>But I don’t recall to have seen such a jump in a plotted
graph?<span> </span>Also anyone has an idea about
that”amount” of
that expected “exothermic” heat??<span> </span></b><br>
</span></p>
<p style="line-height: normal;" class="MsoNormal"><span
style="font-size: 10pt; color:
red;" lang="EN-US">THANKS Chris</span></p>
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