<html><head><meta http-equiv="Content-Type" content="text/html charset=utf-8"></head><body style="word-wrap: break-word; -webkit-nbsp-mode: space; -webkit-line-break: after-white-space;" class=""><div class="">Dear Philip, Crispin and all,</div><div class=""><br class=""></div><div class="">It would not need to be hand held (but nice if it could) as professional stove testing need not be with for everyone. It may require sophisticated equipment. </div><div class="">Crispin has indicated something is up with his group and we should wait until May. From his writing I think I have an idea as to what it might be and I like it. It will likely take longer (it always does) but should be worth waiting for. Best of luck with his group research.</div><div class=""><br class=""></div><div class="">Regards </div><div class=""><br class=""></div><div class="">Frank</div><div class=""><br class=""></div><br class=""><div apple-content-edited="true" class="">
Frank Shields<br class=""><a href="mailto:franke@cruzio.com" class="">franke@cruzio.com</a><br class=""><br class="">
</div>
<br class=""><div><blockquote type="cite" class=""><div class="">On Apr 5, 2015, at 7:41 AM, Philip K. Hopke - phopke <<a href="mailto:phopke@clarkson.edu" class="">phopke@clarkson.edu</a>> wrote:</div><br class="Apple-interchange-newline"><div class=""><div class="WordSection1" style="page: WordSection1; font-family: Helvetica; font-size: 18px; font-style: normal; font-variant: normal; font-weight: normal; letter-spacing: normal; line-height: normal; orphans: auto; text-align: start; text-indent: 0px; text-transform: none; white-space: normal; widows: auto; word-spacing: 0px; -webkit-text-stroke-width: 0px; background-color: rgb(255, 255, 255);"><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="color: rgb(31, 73, 125);" class="">It will not be a hand-held MS It needs too much pumping capability along with other problems to make that small a portable unit.<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="color: rgb(31, 73, 125);" class="">Many of the multiple gas detectors use thermal conductivity, electrochemical, and non-dispersive IR detectors. I have come in late to the discussion so did not see the make and model of the unit being discussed. <o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="color: rgb(31, 73, 125);" class=""> </span></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Philip K. Hopke<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Bayard D. Clarkson Distinguished Professor,<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Director, Center for Air Resources Engineering and Science, and<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Director Institute for a Sustainable Environment<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Clarkson University<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Box 5708<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Potsdam, NY 13699-5708<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">315 268 3861<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Fax: 315 268 4410<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""> </span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Address for Shipments<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Clarkson University<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">8 Clarkson Ave<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Potsdam, NY 13699-5708<o:p class=""></o:p></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="color: rgb(31, 73, 125);" class=""><image001.png></span><span style="font-size: 11pt; font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><o:p class=""></o:p></span></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><span style="color: rgb(31, 73, 125);" class=""> </span></div><div class=""><div style="border-style: solid none none; border-top-color: rgb(181, 196, 223); border-top-width: 1pt; padding: 3pt 0in 0in;" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><b class=""><span style="font-size: 10pt; font-family: Tahoma, sans-serif;" class="">From:</span></b><span style="font-size: 10pt; font-family: Tahoma, sans-serif;" class=""><span class="Apple-converted-space"> </span>Crispin Pemberton-Pigott [<a href="mailto:crispinpigott@outlook.com" class="">mailto:crispinpigott@outlook.com</a>]<span class="Apple-converted-space"> </span><br class=""><b class="">Sent:</b><span class="Apple-converted-space"> </span>Sunday, April 05, 2015 12:58 AM<br class=""><b class="">To:</b><span class="Apple-converted-space"> </span>Frank Shields; Inversiones Falcon; Discussion of biomass cooking stoves; <a href="mailto:franke@cruzio.com" class="">franke@cruzio.com</a> com<br class=""><b class="">Subject:</b><span class="Apple-converted-space"> </span>Re: [Stoves] Testing gases from stoves<o:p class=""></o:p></span></div></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Dear Frank<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">The helium is detected as a carrier gas as far as I know how it works. More on that in May. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">There is a problem in principle with the method you outline below requiring one rather large change to make it work. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">The SeTAR's chemical mass balance test method (currently advertised with a heterogeneous test cycle as the standard burn cycle) is not a<span class="Apple-converted-space"> </span><i class="">carbon mass balance</i> method for a very good reason. Carbon in combustion gases, measured and referenced to a known carbon content of the fuel, making the carbon proxy for fuel gas, doesn't work for biomass combustion in cooking stoves. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Hood-based or stack-based emissions measurements that rely on a carbon mass balance method will<span class="Apple-converted-space"> </span><i class="">only</i> work if the fuel is fed into the fire continuously and the production of carbonaceous ash is produced continuously in a steady state device. That is definitely<span class="Apple-converted-space"> </span><i class="">not</i> a wood-fired cooking stove's mode of operation. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">What I mean is that the fire might burn very well at high power but not be burning much carbon at all. That is the issue. Later it might burn at a lower power but mostly combusting charcoal. In effect the fuel composition (composition of what is burning) changes continuously and the calculation of a carbon-based mass balance method assumes that it be constant. It is not obvious at first when looking at the formulas but it is an underlying assumption. The method assigns to the fuel gases an attribute it may not possess (a constant carbon fraction) something known as a 'category error'. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Under certain conditions, particularly when igniting wet coal with hot wood, or damp wood, the stove will manufacture oxygen and hydrogen from water from an endothermic water gas shift reaction to such an extent that the oxygen level in the stack exceeds the level in ambient air. In this condition all formulas for combustion performance break down and the answers become ridiculous. In fact they are giving wrong answers long before breakdown is reached but it is not obvious.<span class="Apple-converted-space"> </span><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Thus I adopted some years ago a different approach using a total chemical mass balance instead of a carbon mass balance and the calculations not only come right the answers are correct (imagine!)<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">A few people have studied this approach in depth, including Yixiang Zhang, Tafedzwe Makonese, David Beritault, Odnoo in Ulaanbaatar and Harold Annegarn. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">The promise it holds is that the chemical mass balance approach can be applied accurately to the combustion of a fuel that is continuously changing it total chemistry. If you use carbon as a proxy for fuel and the fuel is wood, and the stove is making charcoal, you can calculate a number, no problem, but the number doesn't represent what just happened. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Hood-and-velocity systems and mass balance systems both have significant challenges but 'on balance' mass seems to offer some important advantages, mostly to do with the measurement of condensed volatile particles and the issue of wood (well, damp wood) making O2 and H2. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Paul and Julien and I are considering holding a brief Test Camp at which this would be covered in a minor class on calculating performance outputs. I am in South Africa at the moment discussing changes to the SeTAR method with Harold that will make the approach 'universal', I guess is the right word. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Biomass burned in an inhomogeneous manner presents special problems for the tester that haven't been addressed by methods designed for burning solid fuels in a steady state or liquid fuels at a variable rate. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">The EPA carbon balance methods, for example, give results that are out in excess of 100% of value when applied to some wood stoves, and that is<span class="Apple-converted-space"> </span><i class="">overall</i> with larger errors during the burn. Some overall corrections can be applied after the test but that doesn't address the problem of real time readings which are the basis of gas mass and PM mass totals. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">The chemical mass balance approach seems to offer a way forward. <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Regards<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">Crispin in wonderful windy Muizenberg<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class="">+++++++++<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Calibri, sans-serif; color: rgb(31, 73, 125);" class=""><br class=""><br class=""><o:p class=""></o:p></span></div></div><div id="_originalContent" class=""><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><a href="http://www.hovacinc.com/images/VQM_Comparison_of_Ion_Trap_Quadrupole_Mass_Spectrometers.pdf" style="color: purple; text-decoration: underline;" class="">PDF Granville-Phillips Gas Analysis Products</a><o:p class=""></o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class="">Try the above. Scroll down to a few pages to see what the mass spec will read <o:p class=""></o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class="">Thanks<o:p class=""></o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div><div class=""><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif;">Frank Shields<br class=""><a href="mailto:franke@cruzio.com" style="color: purple; text-decoration: underline;" class="">franke@cruzio.com</a><o:p class=""></o:p></p></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div><div class=""><blockquote style="margin-top: 5pt; margin-bottom: 5pt;" class=""><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class="">On Apr 4, 2015, at 7:28 PM, Inversiones Falcon <<a href="mailto:invfalcones53@yahoo.com" style="color: purple; text-decoration: underline;" class="">invfalcones53@yahoo.com</a>> wrote:<o:p class=""></o:p></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif;" class=""><o:p class=""> </o:p></div><div class=""><div class=""><div class=""><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Hi Frank I did not get any file, will you pleas send it to me.<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Best reagard<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Gustavo<o:p class=""></o:p></span></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div><div id="yui_3_16_0_1_1428200262009_3719" class=""><div id="yui_3_16_0_1_1428200262009_3718" class=""><div id="yui_3_16_0_1_1428200262009_3717" class=""><div class="MsoNormal" align="center" style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; text-align: center; background-color: white; background-position: initial initial; background-repeat: initial initial;"><span style="font-family: Helvetica, sans-serif;" class=""><hr size="1" width="100%" align="center" class=""></span></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><b class=""><span style="font-size: 10pt; font-family: Arial, sans-serif;" class="">From:</span></b><span style="font-size: 10pt; font-family: Arial, sans-serif;" class=""><span class="Apple-converted-space"> </span>Frank Shields <<a href="mailto:franke@cruzio.com" style="color: purple; text-decoration: underline;" class="">franke@cruzio.com</a>><br class=""><b class="">To:</b><span class="Apple-converted-space"> </span>Discussion of biomass cooking stoves <<a href="mailto:stoves@lists.bioenergylists.org" style="color: purple; text-decoration: underline;" class="">stoves@lists.bioenergylists.org</a>>; "<a href="mailto:franke@cruzio.com" style="color: purple; text-decoration: underline;" class="">franke@cruzio.com</a><span class="Apple-converted-space"> </span>com" <<a href="mailto:franke@cruzio.com" style="color: purple; text-decoration: underline;" class="">franke@cruzio.com</a>><span class="Apple-converted-space"> </span><br class=""><b class="">Sent:</b><span class="Apple-converted-space"> </span>Saturday, April 4, 2015 5:12 AM<br class=""><b class="">Subject:</b><span class="Apple-converted-space"> </span>[Stoves] Testing gases from stoves</span><span style="font-family: Helvetica, sans-serif;" class=""><o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3720" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div><div id="yiv0589633299" class=""><div class=""><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white; background-position: initial initial; background-repeat: initial initial;"><span style="font-family: Helvetica, sans-serif;" class=""> </span></p></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div><div id="yiv0589633299" class=""><div id="yui_3_16_0_1_1428200262009_3722" class=""><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Dear Crispin and Stovers,<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> <o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3721" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">I found this to be an interesting report (attached) . I have been looking for a system that would test the combustion gases of interest – and helium. And I found it! It think this system (ion trap mass spectrometer or quadrupole mass spectrometer) may be what’s in Crispin’s hand held tester(?). I think it may teat for helium but, perhaps, is just not set up to do it because ‘Who would want to test helium along with combustion gases?’ – We Would!<span class="Apple-converted-space"> </span><o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3723" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">This could make testing gases much more accurate and easier. How I suggest it working is as follows:<o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3724" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">We pipe in helium at ~ 0.5L/minute into the stove at fuel level in a known and steady rate during the combustion experiment. So we know the total carbon in the stove from the added fuel and the constant rate helium is leaving the stack. We monitor the CO, CO2, H, O2 produced during the experiment and determine their concentrations. The volatile carbon not determined will be tars and other unburned carbon.<o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3725" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">The calculations are: (combustion components) per (helium detected). <o:p class=""></o:p></span></div></div><div id="yui_3_16_0_1_1428200262009_3726" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">This makes it such we do not care about dilution of primary or secondary air. We can make adjustments to them during the experiment and it will not make a difference. We only need to make sure we have complete mixing where we pull out the gas sample for testing. The helium is called a Surrogate Standard and knowing that every minute there is 0.5 liters leaving the stack no matter how diluted or how fast it leaves makes that a solid unit of measure we can ratio the components of interest off. We only need to have the makers of combustion measuring device add helium to the other components of interest and we add helium to the front end of the experiment at a steady known rate. <o:p class=""></o:p></span></div></div><div id="yiv0589633299yqtfd75484" class=""><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> <o:p class=""></o:p></span></div></div></div><div id="yiv0589633299yqtfd96821" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Regards<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> <o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Frank<o:p class=""></o:p></span></div></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> <o:p class=""></o:p></span></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class="">Frank Shields<o:p class=""></o:p></span></div><div class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""><a href="mailto:franke@cruzio.com" target="_blank" style="color: purple; text-decoration: underline;" class="">franke@cruzio.com</a><o:p class=""></o:p></span></div><div id="yiv0589633299yqtfd60543" class=""><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white; background-position: initial initial; background-repeat: initial initial;"><span style="font-family: Helvetica, sans-serif;" class=""> </span></p></div></div><div id="yiv0589633299yqtfd42147" class=""><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div></div></div></div><div style="margin: 0in 0in 0.0001pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white;" class=""><span style="font-family: Helvetica, sans-serif;" class=""> </span></div><div id="yqtfd98269" class=""><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white; background-position: initial initial; background-repeat: initial initial;"><span style="font-family: Helvetica, sans-serif;" class="">_______________________________________________<br class="">Stoves mailing list<br class=""><br class="">to Send a Message to the list, use the email address<br class=""><a href="mailto:stoves@lists.bioenergylists.org" style="color: purple; text-decoration: underline;" class="">stoves@lists.bioenergylists.org</a><br class=""><br class="">to UNSUBSCRIBE or Change your List Settings use the web page<br class=""><a href="http://lists.bioenergylists.org/mailman/listinfo/stoves_lists.bioenergylists.org" target="_blank" style="color: purple; text-decoration: underline;" class="">http://lists.bioenergylists.org/mailman/listinfo/stoves_lists.bioenergylists.org</a><br class=""><br class="">for more Biomass Cooking Stoves, News and Information see our web site:<br class=""><a href="http://stoves.bioenergylists.org/" target="_blank" style="color: purple; text-decoration: underline;" class="">http://stoves.bioenergylists.org/</a><o:p class=""></o:p></span></p></div><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif; background-color: white; background-position: initial initial; background-repeat: initial initial;"><span style="font-family: Helvetica, sans-serif;" class=""> </span></p></div></div></div></div></div><p class="MsoNormal" style="margin: 0in 0in 12pt; font-size: 12pt; font-family: 'Times New Roman', serif;">_______________________________________________<br class="">Stoves mailing list<br class=""><br class="">to Send a Message to the list, use the email address<br class=""><a href="mailto:stoves@lists.bioenergylists.org" style="color: purple; text-decoration: underline;" class="">stoves@lists.bioenergylists.org</a><br class=""><br class="">to UNSUBSCRIBE or Change your List Settings use the web page<br class=""><a href="http://lists.bioenergylists.org/mailman/listinfo/stoves_lists.bioenergylists.org" style="color: purple; text-decoration: underline;" class="">http://lists.bioenergylists.org/mailman/listinfo/stoves_lists.bioenergylists.org</a><br class=""><br class="">for more Biomass Cooking Stoves, News and Information see our web site:<br class=""><a href="http://stoves.bioenergylists.org/" style="color: purple; text-decoration: underline;" class="">http://stoves.bioenergylists.org/</a><o:p class=""></o:p></p></div></blockquote></div><div style="margin: 0in 0in 0.0001pt; 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