[Gasification] Tennessee company - pyrolysis biochar + hydrogen ($1.75 per gallon diesel-equivalent?)

Mark Elliott Ludlow mark at ludlow.com
Wed May 14 21:34:08 CDT 2014


Dear Dr. Karve

I second Art’s assessment. Not every scheme is feasible but I really
appreciate your exploration of the boundaries. I, for one, have learned much
from you over the years.

Best Wishes,

Mark Ludlow

 

From: Gasification [mailto:gasification-bounces at lists.bioenergylists.org] On
Behalf Of Art Krenzel
Sent: Wednesday, May 14, 2014 6:01 PMw
To: Discussion of biomass pyrolysis and gasification
Subject: Re: [Gasification] Tennessee company - pyrolysis biochar + hydrogen
($1.75 per gallon diesel-equivalent?)

 

Dr. Karve,

 

I think you have the "People's Answer"- distributed energy made from
recycled organic materials.  Your work is very important to many people
around the world.  I salute you and your work.

Art 

 




 





> Date: Wed, 14 May 2014 23:26:08 +0530
> From: adkarve at gmail.com <mailto:adkarve at gmail.com> 
> To: gasification at lists.bioenergylists.org
<mailto:gasification at lists.bioenergylists.org> 
> Subject: Re: [Gasification] Tennessee company - pyrolysis biochar +
hydrogen ($1.75 per gallon diesel-equivalent?)
> 
> Dear Art,
> yes I agree with you, that using methane from natural gas would make
> the process simpler and cheaper than using coal. Besides, using coal
> would also involve getting rid of ash. Perhaps, one can produce
> enough methane from agricultural and urban waste, which would make it
> a carbon neutral process.
> Yours
> A.D.Karve
> 
> On Wed, May 14, 2014 at 12:37 PM, Art Krenzel <phoenix98604 at msn.com
<mailto:phoenix98604 at msn.com> > wrote:
> > Dr. Karve,
> >
> > Being able to technically generate hydrogen using incandescent carbon in
a
> > water gas reaction does not make the process economically competitive.
> > Typically, the use of incandescent carbon is a batch, cyclic process
which
> > produces pulses of gases which vary in purity over each cycle
> >
> > Compare the economics of using a batch feedstock which has a variable
> > composition to one which has a very pure, low cost feedstock (CH4) day
in
> > and day out. As a process designer, you can readily see that even
through
> > the chemistry works out to generate hydrogen using incandescent carbon,
the
> > day to day practicality of operating a multistage process with such a
> > variable feedstock is much more difficult and more expensive.
> >
> > Art
> >
> >
> >
> >
> >> Date: Tue, 13 May 2014 06:34:07 +0530
> >> From: adkarve at gmail.com <mailto:adkarve at gmail.com> 
> >> To: gasification at lists.bioenergylists.org
<mailto:gasification at lists.bioenergylists.org> 
> >
> >> Subject: Re: [Gasification] Tennessee company - pyrolysis biochar +
> >> hydrogen ($1.75 per gallon diesel-equivalent?)
> >>
> >> Dear Art,
> >> I am not a chemist but I feel that we can also separate the hydrogen
> >> from water gas. India is the world's third largest producer of
> >> chemical fertilizers and I am quite sure that the Indian fertilizer
> >> producers also use natural gas as their source of hydrogen. India
> >> generates annually about 800 million tonnes of agricultural waste,
> >> which can serve as the source to produce charcoal. This charcoal would
> >> have the same amount of energy as all the petroleum that we import.
> >> We have developed charring kilns for charring light biomass into a
> >> powdery charcoal. currently we briquette it and use it as domestic
> >> fuel. We have also made water gas from our char and demonstrated its
> >> use as fuel.
> >> Yours
> >> A.D.Karve
> >>
> >> On Mon, May 12, 2014 at 10:46 AM, Greg Manning <a31ford at gmail.com
<mailto:a31ford at gmail.com> > wrote:
> >> > Art
> >> >
> >> > Thank you for the explanation,
> >> >
> >> > I knew they used natural gas, but had no idea of the process.
> >> >
> >> > Greg Manning
> >> >
> >> >
> >> > On Sun, May 11, 2014 at 9:28 PM, Art Krenzel <phoenix98604 at msn.com
<mailto:phoenix98604 at msn.com> >
> >> > wrote:
> >> >>
> >> >> Dr. Karve,
> >> >>
> >> >> The Haber Bosch Process is used to convert hydrogen from natural gas
> >> >> and
> >> >> nitrogen from air into ammonia. Yes, it is an energy intensive
process.
> >> >>
> >> >> See: http://en.wikipedia.org/wiki/Haber_process
> >> >>
> >> >> This conversion is typically conducted at 15-25 MPa (2,200-3,600
psi)
> >> >> or
> >> >> 150-250 bar and between 300-550 °C (572-1,022 °F), as the gases are
> >> >> passed
> >> >> over four beds of catalyst, with cooling between each pass so as to
> >> >> maintain
> >> >> a reasonable equilibrium constant. On each pass only about 15%
> >> >> conversion
> >> >> occurs, but any unreacted gases are recycled, and eventually an
overall
> >> >> conversion of 97% is achieved.[1]
> >> >>
> >> >> Art Krenzel
> >> >>
> >> >>
> >> >>
> >> >>
> >> >> > Date: Mon, 12 May 2014 07:29:51 +0530
> >> >> > From: adkarve at gmail.com <mailto:adkarve at gmail.com> 
> >> >> > To: biochar-policy at yahoogroups.com
<mailto:biochar-policy at yahoogroups.com> ;
> >> >> > gasification at lists.bioenergylists.org
<mailto:gasification at lists.bioenergylists.org> 
> >> >> > Subject: Re: [Gasification] Tennessee company - pyrolysis biochar
+
> >> >> > hydrogen ($1.75 per gallon diesel-equivalent?)
> >> >>
> >> >> >
> >> >> > Dear Greg,
> >> >> > the major component of natural gas is methane. How does the
> >> >> > fertilizer
> >> >> > industry separate out hydrogen from methane? The process must be
> >> >> > consuming a lot of energy.
> >> >> > Yours
> >> >> > A.D.Karve
> >> >> >
> >> >> > On Sun, May 11, 2014 at 9:02 AM, Anand Karve <adkarve at gmail.com
<mailto:adkarve at gmail.com> >
> >> >> > wrote:
> >> >> > > Dear List,
> >> >> > > Already in the first decade of the last century, Haber in
Germany
> >> >> > > developed a process for making ammonia by combining nitrogen in
the
> >> >> > > air with hydrogen. I was told that this process is used even
today
> >> >> > > by
> >> >> > > fertilizer manufacturers. Where does the fertilizer industry get
> >> >> > > its
> >> >> > > hydrogen from?
> >> >> > > Yours
> >> >> > > A.D.Karve
> >> >> > >
> >> >> > > On Fri, May 9, 2014 at 8:59 PM, John Bonitz
john.bonitz at gmail.com <mailto:john.bonitz at gmail.com> 
> >> >> > > [biochar-policy] <biochar-policy at yahoogroups.com
<mailto:biochar-policy at yahoogroups.com> > wrote:
> >> >> > >>
> >> >> > >>
> >> >> > >> Return of the Pyromaniax: Proton Power and its hydrous
pyrolysis
> >> >> > >> process for
> >> >> > >> super low-cost hydrogen, by Jim Lane, May 8, 2014
> >> >> > >>
> >> >> > >>
> >> >> > >>
> >> >> > >>
http://www.biofuelsdigest.com/bdigest/2014/05/08/return-of-the-pyromaniax-pr
oton-power-and-its-hydrous-pyrolysis-process-for-super-low-cost-hydrogen/
> >> >> > >>
> >> >> > >>
> >> >> > >>
> >> >> > >> John Bonitz
> >> >> > >> Pittsboro, NC
> >> >> > >>
> >> >> > >> 919-360-2492 | LinkedIn
> >> >> > >>
> >> >> > >> ~~~~~~~~~~~~~
> >> >> > >>
> >> >> > >>
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> >> >> > >
> >> >> > >
> >> >> > > --
> >> >> > > ***
> >> >> > > Dr. A.D. Karve
> >> >> > > Trustee & Founder President, Appropriate Rural Technology
Institute
> >> >> > > (ARTI)
> >> >> >
> >> >> >
> >> >> >
> >> >> > --
> >> >> > ***
> >> >> > Dr. A.D. Karve
> >> >> > Trustee & Founder President, Appropriate Rural Technology
Institute
> >> >> > (ARTI)
> >> >> >
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> >>
> >> --
> >> ***
> >> Dr. A.D. Karve
> >> Trustee & Founder President, Appropriate Rural Technology Institute
(ARTI)
> >>
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> 
> 
> -- 
> ***
> Dr. A.D. Karve
> Trustee & Founder President, Appropriate Rural Technology Institute (ARTI)
> 
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